Well, I only use rock wool in Hydro when growing from seed.... I germ the seeds paper towel style and then use a 1 in cube when a tap root shows...... let it veg and continue the initial sprouting and set the 1 in cube into a larger cube when i think roots will show out the bottom.. I try not to wait till they show...
That did not answer your question though, I am just qualifying where I am coming from..... I usually dont soak my rock wool, I know that maybe I should, but I never have. I also do hydro in tap water so, I am not a purist LOL, however I am looking into a whole house RO water system.
IF you want to soak your rockwool, I would say soak your wool for 24 hours in a water solution of your targeted PH. Rock wool tends to raise PH (brand specific though) on the initial soak..... If you soak in your targetted PH, then that will negate the later raise, or reduce it anyway.